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Research has been ongoing since the s to determine what the proportion of 14 C in the atmosphere has been over the past fifty thousand years. Metal grave goods, for example, cannot be radiocarbon dated, but they may be found in a grave with a coffin, charcoal, or other material which can be assumed to have been deposited at the same time. Errors in procedure can also lead to errors in the results.
The first such published sequence, based on bristlecone pine tree rings, was created by Wesley Ferguson. Then they look for pieces of dead wood which are older than the specimen which they started with and whose tree-ring patterns match up with and overlap those of the first specimen tree-rings can vary greatly in width due to environmental factors and thus produce a pattern by which we can match specimens which grew in the same environment.
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Other materials can present the same problem: It is not always possible to recognize re-use. Robert Lee summed up the reasons behind the controversy over the Carbon dating method in his article "Radiocarbon, Ages in Error," published in the Anthropological Journal of Canada: Carbon dioxide produced in this way diffuses in the atmosphere, is dissolved in the ocean, and is taken up by plants via photosynthesis.
In addition to permitting more accurate dating within archaeological sites than previous methods, it allows comparison of dates of events across great distances. Researchers have studied other radioactive isotopes created by cosmic rays to determine if they could also be used to assist in dating objects of archaeological interest; such isotopes include 3 He , 10 Be , 21 Ne , 26 Al , and 36 Cl.
But that assumes that the amount of carbon in the atmosphere was constant — any variation would speed up or slow down the clock.
These improved field methods were sometimes motivated by attempts to prove that a 14 C date was incorrect. The clock was initially calibrated by dating objects of known age such as Egyptian mummies and bread from Pompeii; work that won Willard Libby the Nobel Prize in Chemistry. For both the gas proportional counter and liquid scintillation counter, what is measured is the number of beta particles detected in a given time period.
In , Thomas Higham and co-workers suggested that many of the dates published for Neanderthal artefacts are too recent because of contamination by "young carbon".
Since the surface ocean is depleted in 14 C because of the marine effect, 14 C is removed from the southern atmosphere more quickly than in the north.
For beta counters, a sample weighing at least 10 grams 0.